The reaction, 

${\mathrm{C}}_6{\mathrm{H}}_6$ + ${\mathrm{CH}}_3\mathrm{Cl}\underset{{\mathrm{AlCl}}_3}{\overset{\mathrm{Anhydrous}}{\to }}$${\mathrm{C}}_6{\mathrm{H}}_5{\mathrm{CH}}_3$ + HCl

is an example of:

1. Friedel-Crafts reaction

2. Kolbe's synthesis

3. Wurtz's reaction

4. Grignard synthesis

Ozonolysis of will give:

1. + 

2. 

3.  

4. none of the above

2-Methylpropene and But-1-ene can be distinguished by -

1. Baeyer's reagent

2. Ammoniacal ${\mathrm{AgNO}}_3$

3. ${\mathrm{Br}}_2$ solution 

4. ${\mathrm{O}}_3$, $\mathrm{Zn}/{\mathrm{H}}_2\mathrm{O}$

An octane number 100 is given to:

1. n-hexane

2. Iso-octane 

3. neo-pentane

4. neo-octane 

Which of the following molecules/species are aromatic in character?

     A                      B                          C                               D

1. B

2. C

3. D

4. A

Xylene, on oxidation with acidic ${\mathrm{KMnO}}_4$, gives:

Nitration of benzene is:

1. nucleophilic substitution

2. electrophilic substitution

3. electrophilic addition

4. nucleophilic addition

Which of the following compounds has the lowest boiling point?

1. ${\mathrm{CH}}_3{\mathrm{CH}}_2{\mathrm{CH}}_2{\mathrm{CH}}_2{\mathrm{CH}}_3$

2. ${\mathrm{CH}}_3\mathrm{CH}=\mathrm{CH}-{\mathrm{CH}}_2{\mathrm{CH}}_3$

3. ${\mathrm{CH}}_3\mathrm{CH}=\mathrm{CH}-\mathrm{CH}={\mathrm{CH}}_2$

4. ${\mathrm{CH}}_3{\mathrm{CH}}_2{\mathrm{CH}}_2{\mathrm{CH}}_3$

1-butyne on reaction with hot alkaline ${\mathrm{KMnO}}_4$ gives:

1. ${\mathrm{CH}}_3{\mathrm{CH}}_2{\mathrm{CH}}_2\mathrm{COOH}$ 

2. ${\mathrm{CH}}_3{\mathrm{CH}}_2\mathrm{COOH}$ + ${\mathrm{CO}}_2$

3. ${\mathrm{CH}}_3{\mathrm{CH}}_2\mathrm{COOH}$

4. ${\mathrm{CH}}_3{\mathrm{CH}}_2\mathrm{COOH}$ + HCOOH

${\mathrm{CH}}_3-\mathrm{C}\equiv \mathrm{C}-{\mathrm{CH}}_3\stackrel{{\mathrm{NaNH}}_2}{\to }$ X; what is X?

1. ${\mathrm{CH}}_3-{\mathrm{CH}}_2{\mathrm{CH}}_2{\mathrm{CH}}_3$

2. ${\mathrm{CH}}_3{\mathrm{CH}}_2\mathrm{C}\equiv \mathrm{CH}$

3. 

4. ${\mathrm{CH}}_2=\mathrm{C}=\mathrm{CH}-{\mathrm{CH}}_3$