Amongst the given set of reactants, the most appropriate for preparing 2o amine is: 

1. 2o  R - Br + NH3
2. 2oR — Br + NaCN followed by H2/Pt
3. 1o R —NH2 + RCHO followed by H2/Pt
4. 1o R — Br(2 mol) + potassium phthalimide followed by H3O+/ heat