The compound obtained by heating a mixture of primary amine and chloroform with ethanolic potassium hydroxide (KOH) is                                                                          

1. an alkyl isocyanide

2. an alkyl halide

3. an amide

4. an amide and nitro compound

Nitrobenzene on reaction with conc. HNO₃/H₂SO₄ at 80-100$°$C forms -

1. 1,2-Dinitrobenzene

2. 1,3-Dinitrobenzene

3. 1,4-Dinitrobenzene

4. 1,2,4-Trinitrobenzene

Ethyl chloride is converted into diethyl ether by -                                                  

 1. Wurtz reaction                           
 2. Grignard reaction
 3. Perkin's reaction                       
 4. Williamson's synthesis

Consider the following reaction,

Phenol$\stackrel{\mathrm{Zn}-\mathrm{dust}}{\to }$X$\underset{\mathrm{Anhy}.{\mathrm{AlCl}}_3}{\overset{{\mathrm{CH}}_3\mathrm{Cl}}{\to }}$Y$\stackrel{\mathrm{Alk}.{\mathrm{KMnO}}_4}{\to }$Z 

The product Z is                            

1. toluene

2. benzaldehyde

3. benzoic acid

4. benzene

In this reaction, CH₃CHO + HCN$\to$CH₃CH(OH)CN$\stackrel{\mathrm{H}.\mathrm{OH}}{\to }$CH₃CH(OH)COOH an asymmetric centre is generated. The acid obtained would be                                                                      

1. 50% D + 50% L-isomer

2. 20%D + 80% L-isomer

3. D-isomer

4. L-isomer

The -OH group of an alcohol or the -COOH group of a carboxylic acid can be replaced by -Cl using     

1. phosphorus pentachloride

2. hypochlorous acid

3. chlorine

4. hydrochloric acid

What ester produces a white crystalline acid when boiled with KOH, cooled, and acidified with conc. HCl?

1. Methyl acetate 

2. Ethyl acetate

3. Ethyl formate 

4. Ethyl benzoate

The compound formed when malonic acid heated with urea, is                  

1. cinnamic acid

2. butyric acid

3. barbituric acid

4. crotonic acid

The dihedral angle between two C-H bonds in the staggered conformation of ethane  is            

1. 60$°$ 

2. 180$°$

3. 0$°$ 

4. 120$°$

Number of monochlorinated products (excluding stereo-isomers) obtained from the given reaction are :