The major organic product formed from the following reaction

 $\underset{\left(\mathrm{ii}\right) {\mathrm{LiAlH}}_4 \left(\mathrm{iii}\right) {\mathrm{H}}_2\mathrm{O}}{\overset{\left(\mathrm{i}\right) {\mathrm{CH}}_3{\mathrm{NH}}_2}{\to }}$ ... is

1.                   

2.  

3.                 

4.  

 

Benzoic acid gives benzene on being heated with X and phenol gives benzene on being heated with Y. Therefore, X and Y are respectively                                                              

1. Sodalime and copper

2. Zn dust and NaOH

3. Cu and sodalime

4. Sodalime and zinc dust

Which one of the following on oxidation gives a ketone?                       

1. primary alcohol                     

2. secondary alcohol

3. tertiary alcohol                     

4. All of these

A carbonyl compound reacts with hydrogen cyanide to form cyanohydrin which on hydrolysis forms a racemic mixture of $\mathrm{\alpha }$-hydroxy acid. The carbonyl compound is

1. acetaldehyde 

2. acetone

3. diethyl ketone 

4. formaldehyde                              

Consider the following transformations

CH₃COOH $\stackrel{{\mathrm{CaCO}}_3}{\to }$A$\stackrel{\mathrm{heat}}{\to }$B$\underset{\mathrm{NaOH}}{\overset{{\mathrm{I}}_2}{\to }}$C The molecular formula of C is                       

1. ${\mathrm{CH}}_3-\underset{\mathrm{I}}{\overset{\mathrm{OH}}{\underset{\left|}{\overset{\right|}{\mathrm{C}}}}}-{\mathrm{CH}}_3$

2. ${\mathrm{ICH}}_2-{\mathrm{COCH}}_3$

3. ${\mathrm{CHI}}_3$

4. ${\mathrm{CH}}_3\mathrm{I}$

 A and B in the following reactions are $\underset{\mathrm{KCN}}{\overset{\mathrm{HCN}/}{\to }}$A$\stackrel{\mathrm{B}}{\to }$

1. A=${\mathrm{RR}}^{\text{'}}{\mathrm{CH}}_2\mathrm{CN}$, B=NaOH

2. A=, B=${\mathrm{CH}}_3$

3. A=, B=${\mathrm{CH}}_3$

4. A=, B=${\mathrm{LiAlH}}_4$

The product formed in aldol condensation is                                                                 

1. a beta-hydroxy acid

2. a beta-hydroxy aldehyde or a beta-hydroxy ketone

3. an alpha-hydroxy aldehyde or ketone

4. an alpha, beta unsaturated ester

Consider the following reaction,

Phenol$\stackrel{\mathrm{Zn}-\mathrm{dust}}{\to }$X$\underset{\mathrm{Anhy}.{\mathrm{AlCl}}_3}{\overset{{\mathrm{CH}}_3\mathrm{Cl}}{\to }}$Y$\stackrel{\mathrm{Alk}.{\mathrm{KMnO}}_4}{\to }$Z 

The product Z is                            

1. toluene

2. benzaldehyde

3. benzoic acid

4. benzene

Reduction of aldehydes and ketones into hydrocarbons using zinc amalgam and conc. HCl is called    

1. Clemmenson reduction

2. Cope reduction

3. Dow reduction

4. Wolff-Kishner reduction

Aldol condensation will not take place in

1. HCHO 

2. ${\mathrm{CH}}_3\mathrm{CHO}$

3. ${\mathrm{CH}}_3{\mathrm{COCH}}_3$

4. ${\mathrm{CH}}_3{\mathrm{CH}}_2\mathrm{CHO}$