The correct representation of an exothermic reaction is:

1.  2.
3. 4. Both 1 and 2

Subtopic:  Arrhenius Equation |
 86%
Level 1: 80%+
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Rate law for the reaction \(A+2 B \rightarrow C\) is found to be
Rate = k[A][B]
If the concentration of reactant 'B' is doubled, keeping the concentration of A constant, then the value of the rate of the reaction will  be:

1. The same. 2. Doubled.
3. Quadrupled. 4. Halved.
Subtopic:  Definition, Rate Constant, Rate Law |
 77%
Level 2: 60%+
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An incorrect statement about the collision theory of chemical reaction is:

1. It considers reacting molecules or atoms to be hard spheres and ignores their structural features.
2. The number of effective collisions determines the rate of reaction.
3. The collision of atoms or molecules possessing sufficient threshold energy results in product formation.
4. Molecules should collide in the proper orientation for the collision to be effective with sufficient threshold energy and proper orientation.
Subtopic:  Arrhenius Equation |
Level 3: 35%-60%
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A first-order reaction is 50 % completed in 1.26 × 1014 s. The time required for 100 % completion of the reaction will be:

1. 1.26 × 1015 s

2. 2.52 × 1014 s

3. 2.52 × 1028 s

4. Infinite

Subtopic:  First Order Reaction Kinetics |
 77%
Level 2: 60%+
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Compounds A and B react according to the following chemical equation.

A(g) + 2B(g)  2C(g)

The concentration of either A or B was changed keeping the concentrations of one of the reactants constant and rates were measured as a function of initial concentration. The following results were obtained. Choose the correct option for the rate equations for this reaction.

Experiment Initial
concentration of
[A]/mol L–1
Initial
concentration of
[B]/moI L–1
Initial
rate (mol L–1 s–1)
1.
2.
3.
0.30
0.30
0.60
0.30
0.60
0.30
0.10
0.40
0.20
1. Rate=kA2B
2. Rate=kAB2
3. Rate=kAB
4. Rate=kA2B0

Subtopic:  Definition, Rate Constant, Rate Law |
 88%
Level 1: 80%+
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An incorrect statement regarding a catalyst is:

1. It catalyzes the forward and backward reactions to the same extent.
2. It alters the Gibbs free energy of the reaction.
3. It is a substance that does not change the equilibrium constant of a reaction.
4. It provides an alternate mechanism by reducing activation energy between reactants and products.
Subtopic:  Catalyst |
 82%
Level 1: 80%+
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Consider the reaction AB. The concentration of both the reactant and the product varies exponentially with time.

The graph that accurately depicts how reactant and product concentrations change with time is:

1.  2.
3. 4.
Subtopic:  Definition, Rate Constant, Rate Law |
 85%
Level 1: 80%+
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The graphs that represent a zero-order reaction are:

(a) (b)
(c) (d)
 
1. a and b 2. b and c
3. c and d 4. a and d
Subtopic:  Order, Molecularity and Mechanism |
Level 3: 35%-60%
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The correct graphical representation of first-order reaction is:

(a)  (b)
(c) (d)

   

1. (a) and (b) 2. (b) and (c)
3. (c) and (d) 4. (a) and (d)
Subtopic:  First Order Reaction Kinetics |
 83%
Level 1: 80%+
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Match the graph given in Column I with the order of reaction given in Column II.
More than one item in Column I may be linked to the same item in Column II:

Column I Column II
(i) (a) 1st order
(ii) (b) Zero order
(iii)
(iv)
 
 
(i) (ii) (iii) (iv)
1. (a) (b) (a) (b)
2. (a) (b) (b) (a)
3. (a) (a) (b) (b)
4. (b) (b) (a) (a)
Subtopic:  Order, Molecularity and Mechanism |
 76%
Level 2: 60%+
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