The molar conductances of Ba2+ and Cl- 127 and 76Ω-1 cm-1 mol-1 respectively at infinite dilution. The equivalent conductance of BaCl2 at infinite dilution will be
1. 139.52
2. 203
3. 279
4. 101.5
An increase in equivalent conductance of a strong electrolyte with dilution is mainly due to
1. increase in ionic mobility of ions
2. 100% ionisation of electrolyte at normal dilution
3. increase in both, i.e. number of ions and ionic mobility of ions
4. increase in number of ions
What will be the molar conductance at infinite dilution for NH4OH. If at infinite dilution the molar conductances of Ba(OH)2, BaCl2 and NH4Cl are 523.28, 280.0 and 129.8 ohm-1 cm-1 mol-1 respectively.
1. 502.88
2. 373.68
3. 251.44
3. 226.96
At 25° C molar conductance of 0.1 molar aqueous solution of ammonium hydroxide is
9.54 ohm1cm2mol-1 and at infinite dilution its molar conductance is 238 ohm1cm2mol-1.
The degree of ionisation of ammonium hydroxide at the same concentration and
temperature is
1. 2.080%
2. 20.800%
3. 4.008%
4. 40.800%
Limiting molar conductivity of NH4OH (i.e Åm(NH4OH)) is equal to:-
1. Åm (NH4Cl)+Åm(NaCl)-Åm(NaOH)
2. Åm(NaOH)+Åm(NaCl)-Åm(NH4Cl)
3. Åm(NH4OH)+Åm(NH4Cl)-Åm(HCl)
4. Å(NH4Cl)+Å(NaOH)-Å(NaCl)
Kohlrausch's law states that at
(1) finite dilution, each ion makes definite contribution to equivalent conductance of an electrolyte, whatever be the nature of the other ion of the electrolyte.
(2) infinite dilution, each ion makes definite contribution to equivalent conductance of an electrolyte depending on the nature of the other ion of th electrolyte.
(3) infinite dilution, each ion makes definite contribution to conductance of an electrolyte whatever be the nature of the other ion of the electrolyte.
(4) infinite dilution, each ion makes definite contribution to equivalent conductance of an electrolyte, whatever be the nature of the other ion of the electrolyte.
Value of \(\land_{m}^{0}\) for \(\) \(SrCl_{2}\) (strong electrolyte) in water at 25°C from the data below is:
| Conc. (mol/litre) | 0.25 | 1 |
| \(\land_{m} \Omega^{- 1 } c m^{2 } m o l^{- 1}\) | 260 | 250 |
1. 270 Ω-1 cm2 mol-1
2. 260 Ω-1 cm2 mol-1
3. 250 Ω-1 cm2 mol-1
4. 255 Ω-1 cm2 mol-1
Limiting molar conductivity of NH4OH (i.e., is equal to -
1.
2.
3.
4.
The molar conductance of solution of a weak monobasic acid is 8.0 ohm-1 cm2 and at infinite dilution is 400 ohm-1 cm2. The dissociation constant of this acid is:
| 1. | \(1.25 \times10^{-5}\) | 2. | \(1.25 \times10^{-6}\) |
| 3. | \(6.25 \times10^{-4}\) | 4. | \(1.25 \times10^{-4}\) |