The value of Henry's constant K_H -

1. Increases with increase in temperature.

2. Decreases with increase in temperature.

3. Remains constant.

4. First increases then decreases.

The mole fraction of ethylene glycol (C₂H₆O₂) in a solution containing 20% of C₂H₆O₂ by mass is-

1. 0.932

2. 0.0672

3. 0.832

4. 0.732

If N₂ gas is bubbled through water at 293 K, how many millimoles of N₂ gas would dissolve in 1 litre of water?
(Partial pressure of nitrogen = 0.987 bar, Henry’s law constant for N₂ at 293 K = 76.48 kbar).

1. 0.716 mmol

2. 0.616 mmol

3. 0.726 mmol

4. 0.516 mmol

The mixture that shows positive deviation from Raoult's law is-

1. Benzene + Toluene

2. Acetone + Chloroform

3. Chloroethane + Bromoethane

4. Ethanol + Acetone

The correct option for the value of vapor pressure of a solution at 45 $°$C with benzene to octane in a molar ratio 3:2 is:

[At 45 $°$C vapor pressure of benzene is 280 mm Hg and that of octane is 420 mm Hg. Assume Ideal gas]
1. 336 mm of Hg
2. 350 mm of Hg
3. 160 mm of Hg
4. 168 mm of Hg

The partial pressure of ethane over a saturated solution containing 6.56 X 10^-2 g of ethane is 1 bar. If the solution contains 5.00 X 10^-2 g of ethane, then what shall be the partial pressure of the gas?

1. 0.76 bar

2. 0.16 bar

3. 1.16 bar

4. 3.12 bar

On mixing, heptane, and octane form an ideal solution at 373 K, the vapor pressures of the two liquid components (Heptane and octane) are 105 kPa and 45 kPa respectively. Vapour pressure of the solution obtained by mixing 25.0 g of heptane and 35 g of octane will be:
(molar mass of heptane = 100 g mol⁻¹ and of octane =114 g 1 mol⁻¹)

1. 144.5 kPa

2. 72.0 kPa

3. 36.1 kPa

4. 96.2 kPa

If 8 g of a non-electrolyte solute is dissolved in 114 g of n-octane to reduce its vapor pressure to 80 %, the molar mass (in g mol^–1) of the solute is -

[Molar mass of n-octane is 114 g mol^–1]