Q. No.A solution containing 10 g/dm3 of urea (molecular mass = 60 g mol-1) is isotonic with a 5 % solution of a non-volatile solute. The molecular mass of this non-volatile solute is:
| 1. | 25 g mol-1 | 2. | 300 g mol-1 |
| 3. | 350 g mol-1 | 4. | 200 g mol-1 |
1. \(\Delta H_{mix}\)
2. \(\Delta S_{mix}\)
3. \(\Delta V_{mix}\)
4. \(\Delta P=P_{\text{observed}}-P_{\text{Raoult}}\)
| Type of solution | Example |
| a. Solid in gas | i. Aerated water |
| b. Gas in liquid | ii. Smoke |
| c. Liquid in solid | iii. Solution of hydrogen in palladium |
| d. Gas in solid | iv. Amalgams |
| a | b | c | d | |
| 1. | i | iii | iv | ii |
| 2. | ii | i | iv | iii |
| 3. | iii | i | iv | ii |
| 4. | iv | i | ii | iii |
The example of gas in a solid type solution is:
1. Solution of hydrogen in palladium.
2. Ethanol dissolved in water.
3. Camphor vapours in N2 gas.
4. Amalgams.
Colligative properties depend on:
| 1. | The nature of the solute particles dissolved in the solution. |
| 2. | The number of solute particles in the solution. |
| 3. | The physical properties of the solute particles dissolved in the solution. |
| 4. | The nature of solvent particles. |
The solubility of a gas in a liquid decreases with an increase in temperature because:
| 1. | Dissolution of a gas in a liquid is an endothermic process. |
| 2. | Dissolution of a gas in a liquid is an exothermic process. |
| 3. | Gases are highly compressible. |
| 4. | All of the above. |
An aqueous solution of hydrochloric acid -
1. Obeys Raoult's law
2. Shows negative deviations from Raoult's law
3. Shows positive deviations from Raoult's law
4. Obeys Henry's law at all compositions
Consider the following statements about the composition of the vapour over an ideal 1:1 molar mixture of benzene and toluene. The correct statement is:
Assume that the temperature is constant at 25 oC.
(Given, vapour pressure data at 25 °C, benzene = 12.8 kPa, toluene = 3.85 kPa)
| 1. | The vapour will contain a higher percentage of toluene. |
| 2. | The vapour will contain equal amounts of benzene and toluene. |
| 3. | Not enough information is given to make a prediction. |
| 4. | The vapour will contain a higher percentage of benzene. |
The insoluble compound in water is /are
1. Phenol
2. Formic acid and toluene
3. Phenol and toluene
4. Toluene and chloroform
The maximum amount of a solid solute that can be dissolved in a specified amount of a given liquid solvent does not depend upon -
| 1. | Temperature | 2. | Nature of solute |
| 3. | Pressure | 4. | Nature of solvent |
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