- 1(current)
Q. No.Which of the following statements is not true for the rate constant, k?
| 1. | large value of k indicates fast reactions. |
| 2. | The value of k is independent of the concentration of reactants |
| 3. | The value of k is independent of the concentration of products |
| 4. | The value of the rate constant, k, as the name suggests is always constant for a particular reaction at all temperatures. |
Subtopic: Arrhenius Equation |
72%
Level 2: 60%+
Hints
| Assertion (A): | For an endothermic reaction, the potential energy of the reactant is more than the potential energy of the product. |
| Reason (R): | Reactant molecules, before converting to products, form an activated complex that has lower energy than reactants as well as the products. |
| 1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
| 2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
| 3. | (A) is True but (R) is False. |
| 4. | Both (A) and (R) are False. |
Subtopic: Arrhenius Equation |
64%
Level 2: 60%+
Hints
The rate of a reaction is decreased by 3.555 times when the temperature was changed from 40°C to 30°C. The activation energy (in kJ ) of the reaction is:
(Take R=8.314 J In 3.555=1.268)
1. 100 kJ/mol
2. 120 kJ/mol
3. 95 kJ/mol
4. 108 kJ/mol
Subtopic: Arrhenius Equation |
Level 3: 35%-60%
JEE
Hints
The rate constant, the activation energy and the Arrhenius parameter of a chemical reaction at \(25^{\circ}C\) are \(3\times10^{-4}~s^{-1},104.4~kJ~mol^{-1}\) and \(6\times10^{14}~s^{-1}\) respectively. The value of the rate constant as \(T\rightarrow\infty\) is
1. \(2\times10^{18}~s^{-1}\)
2. \(6\times10^{14}~s^{-1}\)
3. \(\infty\)
4. \(3.6\times10^{30}~s^{-1}\)
1. \(2\times10^{18}~s^{-1}\)
2. \(6\times10^{14}~s^{-1}\)
3. \(\infty\)
4. \(3.6\times10^{30}~s^{-1}\)
Subtopic: Arrhenius Equation |
76%
Level 2: 60%+
Hints
What is the pre-exponential factor for a reaction at 500 K with a rate constant of 0.02 s⁻¹ and an activation energy of 18.230 kJ?
1. 1.61
2. 1.41
3. 1.81
4. 1.21
1. 1.61
2. 1.41
3. 1.81
4. 1.21
Subtopic: Arrhenius Equation |
Level 3: 35%-60%
Hints
- 1(current)
Q. No.
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