\(Fe^{2+}(aq) \ + \ Ag^{+}(aq) \ \rightarrow \ Fe^{3+}(aq) \ + \ Ag(s)\)

\(E_{Fe^{3+}/Fe^{2+}}^{o} \ = \ 0.77 \ V; \ E_{Ag^{+}/Ag}^{o} \ = \ 0.80 \ V\)

The value of \(\Delta G_{r}^{o} \)  in 
the above reaction will be:

1. +2.89 kJ

2. -2.89 kJ

3. -2.89 J

4. -186.83 J

Subtopic:  Relation between Emf, G, Kc & pH |
 84%
Level 1: 80%+
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Given:
(i) Cu2++2e-Cu    Eo = 0.337 V 
(ii) Cu2++e-Cu+  Eo = 0.153 V 
Electrode potential, Eo for the reaction, 
Cu++e-Cu, will be: 

1. 0.52 V

2. 0.90 V

3. 0.30 V

4. 0.38 V

Subtopic:  Relation between Emf, G, Kc & pH |
 76%
Level 2: 60%+
AIPMT - 2009
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What is the correct order of ionic mobility of the following ions in an aqueous solution?
1. K+> Na+> Rb+> Cs+ 2. Cs+> Rb+> K+> Na+
3. Rb+> K+> Cs+> Na+ 4. Na+> K+> Rb+> Cs+
Subtopic:  Relation between Emf, G, Kc & pH |
 73%
Level 2: 60%+
AIPMT - 2008
Hints

Given the following cell reaction:
 \(\mathrm{2Fe^{3+}(aq) \ + \ 2I^{-}(aq)\rightarrow 2Fe^{2+}(aq) \ + \ I_{2}(aq)}\)

  \(E_{cell}^{o} \ = \ 0.24 \ V\) at \(298\) \(K\).
The standard Gibbs energy ∆rG of the cell reaction is:

[Given: \(F  = 96500\) \(C\) \(mol^{- 1}\)]

1. \(23 . 16\) \(kJ\) \(mol^{- 1}\)

2. \(- 46 . 32\) \(kJ\) \(mol^{- 1}\)

3. \(- 23 . 16\) \(kJ\) \(mol^{- 1}\)

4. \(46 . 32\) \(kJ\) \(mol^{- 1}\)

Subtopic:  Relation between Emf, G, Kc & pH |
 75%
Level 2: 60%+
NEET - 2019
Hints

For a cell involving one electron \(E_{cell}^{\ominus} = 0 . 59  V\) at 298 K. The equilibrium constant for the cell reaction is :
\(\mathrm{[Given~ that~ \frac {2.303 ~RT}{F} = 0.059 ~V~ at~ T = 298 K]}\)

1. \(1 . 0 \times \left(10\right)^{30}\) 2. \(1 . 0 \times \left(10\right)^{2}\)
3. \(1 . 0 \times \left(10\right)^{5}\) 4. \(1 . 0 \times \left(10\right)^{10}\)

Subtopic:  Relation between Emf, G, Kc & pH |
 73%
Level 2: 60%+
NEET - 2019
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Links

On the electrolysis of brine (aq NaCl solution):
1. pH of the solution will rise. 2. pH of the solution will fall.
3. No change in the pH of the solution. 4. None of the above.

Subtopic:  Relation between Emf, G, Kc & pH |
 64%
Level 2: 60%+
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