1. | Vinylic halide | 2. | Benzylic halide |
3. | Aryl halide | 4. | Allylic halide |
(i) | (ii) |
(iii) |
1. | (i) < (ii) < (iii) | 2. | (ii) < (i) < (iii) |
3. | (iii) < (ii) < (i) | 4. | (ii) < (iii) < (i) |
1. | (D) only | 2. | (C) and (D) only |
3. | (B) only | 4. | (A) and (B) only |
1. | 2. | ||
3. | 4. |
1. | |
2. | Benzene, Cl2, anhydrous FeCl3 |
3. | Phenol, NaNO2, HCl, CuCl |
4. |
1. | A racemic mixture shows zero optical rotation |
2. | SN1 reaction yields a 1:1 mixture of both enantiomers |
3. | The product obtained by SN2 reaction of haloalkane having chirality at the reactive site shows the inversion of configuration |
4. | Enantiomers are superimposable mirror images on each other |
The correct reaction among the following is:
1. | |
2. | |
3. | \(2CH_3CH_2Br\xrightarrow[dry~ether]{Mg}CH_3CH_2CH_2CH_3\) |
4. | \(2CH_3CH_2Br\xrightarrow[Ethanol]{Na}CH_3CH_2CH_2CH_3\) |
The product formed in the following reaction sequence is:
1. | |
2. | \(CH_3-CH=CH-CH_3 \) |
3. | \(CH_3 -CH_2 -CH = CH_2 \) |
4. | \(CH_3 -CH_2 -CH_2 -CH_2 -OH \) |
1. | (IV) > (III) > (II) > (I) |
2. | (I) > (II) > (III) > (IV) |
3. | (I) > (III) > (II) > (IV) |
4. | (IV) > (II) > (III) > (I) |
Assertion (A): | Chlorine is an electron-withdrawing group but it is ortho, para directing in electrophilic aromatic substitution. |
Reason (R): | Inductive effect of chlorine destabilises the intermediate carbocation formed during the electrophilic substitution, however due to the more pronounced resonance effect, the halogen stabilises the carbocation at ortho and para positions. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |