The equilibrium constant Kc expression for the above mentioned reaction is:
are the respective ionisation constants for the following reactions.
\(\mathrm{H}_2 \mathrm{~S} \rightleftharpoons \mathrm{H}^{+}+\mathrm{HS}^{-}\)
\(\mathrm{HS}^{-} \rightleftharpoons \mathrm{H}^{+}+\mathrm{S}^{2-}\)
\(\mathrm{H}_2 \mathrm{~S} \rightleftharpoons 2 \mathrm{H}^{+}+\mathrm{S}^{2-}\)
The correct relationship between is:
1. | \(\mathrm{K}_{\mathrm{a}_3}=\mathrm{K}_{\mathrm{a}_1} \times \mathrm{K}_{\mathrm{a}_2} \) | 2. | \(\mathrm{K}_{\mathrm{a}_3}=\mathrm{K}_{\mathrm{a}_1}+\mathrm{K}_{\mathrm{a}_2} \) |
3. | \(K_{a_3}=K_{a_1}-K_{a_2} \) | 4. | \(\mathrm{K}_{\mathrm{a}_3}=\mathrm{K}_{\mathrm{a}_1} / \mathrm{K}_{\mathrm{a}_2}\) |
Reaction quotient for the reaction, is given by , .The reaction will proceed from right to left if Kc value is:
1. | Q<Kc | 2. | Q=0 |
3. | Q>Kc | 4. | Q=Kc |
In the reaction A(g) + 2B(g) ⇌ 2C(g) + D(g), the initial concentration of B is twice that of A and, at equilibrium, the concentrations of A and D are equal. The value of the equilibrium constant will be:
1. | 4 | 2. | 16 |
3. | 2 | 4. | 1 |
For the following reaction,
H
The effect on the state of equilibrium on doubling the volume of the system will be:
1. | Shift to the reactant side | 2. | Shift to the product side |
3. | No effect on the state of equilibrium | 4. | Liquefaction of HI |
Given a hypothetical reaction :
More could be produced at equilibrium by :
1. | Using a catalyst | 2. | Removing some of B2 gas |
3. | Increasing the temperature | 4. | Increasing the pressure |
(a) PCl5 (g) PCl3 (g) + Cl2 (g)
(b) CaO (s) + CO2 (g) CaCO3 (s)
(c) 3Fe (s) + 4H2O (g) Fe3O4 (s) + 4H2 (g)
The effect of an increase in the volume on the number of moles of products in the above-mentioned reactions would be, respectively:
1. a) Increase, b) decrease, c) same
2. a) Decrease, b) same, c) increase
3. a) Increase, b) increase, c) same
4. a) Increase, b) decrease, c) increase
The equilibrium reaction that doesn't have equal values for Kc and Kp is:
1. \(2NO(g) \rightleftharpoons N_2(g) + O_2(g)\)
2. \(SO_2(g) + NO_2(g) \rightleftharpoons SO_3(g) + NO(g)\)
3. \(H_2(g) + I_2(g) \rightleftharpoons 2HI (g)\)
4. \(2C(s) + O_2(g) \rightleftharpoons 2CO_2(g)\)
For the reaction the equilibrium constant is K1. The equilibrium constant is K2 for the reaction
The value of K for the reaction given below will be:
1.
2.
3.
4.
For the reaction 2NOCl(g)⇔2NO(g)+Cl2(g), KC at 427C is \(3\times 10^{-6} \ mol\ L^{-1}\). The value of Kp will be :
1.
2.
3.
4.