I2(s) + 5F2(g)  2IF5(g) 

The equilibrium constant Kc expression for the above mentioned reaction is:

1. KC= IF52F25
2. KC= IF52F25I2
3. KC =F25I2IF22
4.  KC =F25IF52

Subtopic:  Introduction To Equilibrium |
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Ka1, Ka2 and Ka3 are the respective ionisation constants for the following reactions.
\(\mathrm{H}_2 \mathrm{~S} \rightleftharpoons \mathrm{H}^{+}+\mathrm{HS}^{-}\)
\(\mathrm{HS}^{-} \rightleftharpoons \mathrm{H}^{+}+\mathrm{S}^{2-}\)
\(\mathrm{H}_2 \mathrm{~S} \rightleftharpoons 2 \mathrm{H}^{+}+\mathrm{S}^{2-}\)
The correct relationship between Ka1, Ka2 and Ka3 is:

1. \(\mathrm{K}_{\mathrm{a}_3}=\mathrm{K}_{\mathrm{a}_1} \times \mathrm{K}_{\mathrm{a}_2} \) 2. \(\mathrm{K}_{\mathrm{a}_3}=\mathrm{K}_{\mathrm{a}_1}+\mathrm{K}_{\mathrm{a}_2} \)
3. \(K_{a_3}=K_{a_1}-K_{a_2} \) 4. \(\mathrm{K}_{\mathrm{a}_3}=\mathrm{K}_{\mathrm{a}_1} / \mathrm{K}_{\mathrm{a}_2}\)
Subtopic:  Introduction To Equilibrium |
 80%
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Reaction quotient for the reaction, N2(g)+3H2(g)2NH3(g) is given by , Q = [NH3]2[N2][H2]3 .The reaction will proceed from right to left if Kc value is:

1. Q<Kc  2. Q=0
3. Q>Kc  4. Q=Kc 
Subtopic:  Introduction To Equilibrium |
 73%
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In the reaction A(g) + 2B(g) ⇌ 2C(g) + D(g), the initial concentration of B is twice that of A and, at equilibrium, the concentrations of A and D are equal. The value of the equilibrium constant will be:

1. 4 2. 16
3. 2 4. 1
Subtopic:  Introduction To Equilibrium |
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For the following reaction, 
 H2(g)+I2(g)2HI(g) at 250°C,

The effect on the state of equilibrium on doubling the volume of the system will be:

1. Shift to the reactant side 2. Shift to the product side 
3. No effect on the state of equilibrium 4. Liquefaction of HI

Subtopic:  Le Chatelier's principle |
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Given a hypothetical reaction :
AB2g+12B2gAB3g; H=-x kJ
More  could be produced at equilibrium by :

1. Using a catalyst 2. Removing some of Bgas
3. Increasing the temperature 4. Increasing the pressure
Subtopic:  Le Chatelier's principle |
 75%
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(a) PCl5 (g) PCl3 (g) + Cl2 (g)

(b) CaO (s) + CO2 (g)   CaCO3 (s)

(c) 3Fe (s) + 4H2O (g)  Fe3O4 (s) + 4H2 (g)

The effect of an increase in the volume on the number of moles of products in the above-mentioned reactions would be, respectively:

1. a) Increase,  b) decrease, c) same

2. a) Decrease,  b) same, c) increase

3. a) Increase,  b) increase, c) same

4. a) Increase,  b) decrease, c) increase

Subtopic:  Le Chatelier's principle |
 70%
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The equilibrium reaction that doesn't have equal values for Kc and Kis: 

1. \(2NO(g) \rightleftharpoons N_2(g) + O_2(g)\)
2. \(SO_2(g) + NO_2(g) \rightleftharpoons SO_3(g) + NO(g)\)
3. \(H_2(g) + I_2(g) \rightleftharpoons 2HI (g)\)
4. \(2C(s) + O_2(g) \rightleftharpoons 2CO_2(g)\)

Subtopic:  Kp, Kc & Factors Affecting them |
 90%
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AIPMT - 2010
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For the reaction N2(g) + O2(g)2NO(g) the equilibrium constant is K1. The equilibrium constant is K2 for the reaction  2NO(g) + O2(g) 2NO2(g) 
The value of K for the reaction given below will be:
NO2(g)12N2(g) +O2(g) 

1.  14 4 K1 K2

2.  1K1K21/2

3.  1K1K2

4.  12K1K2

Subtopic:  Kp, Kc & Factors Affecting them |
 88%
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AIPMT - 2011
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For the reaction 2NOCl(g)⇔2NO(g)+Cl2(g), KC at 427°C is \(3\times 10^{-6} \ mol\ L^{-1}\). The value of Kp will be :

1. 1.72×10-4

2. 7.50×105

3. 2.50×10-5

4. 2.50×10-4

Subtopic:  Kp, Kc & Factors Affecting them |
 84%
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