Amongst the given option which of the following molecules/ion acts as a Lewis acid? 
1. \(OH^- \) 2. \(NH_3 \)
3. \(H_2O \) 4. \(BF_3 \)
Subtopic:  Acids & Bases - Definitions & Classification |
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The equilibrium concentration of the species in the reaction \(A+B \rightleftharpoons C+D\) are 2, 3, 10 and 6 mol L-1, respectively at 300 K .\(\Delta G^o\) for the reaction is: (R = 2 cal/mol K) 
1. -13.73 cal  2. 1372.60 cal 
3. -137.26 cal  4. -1381.80 cal
Subtopic:  Introduction To Equilibrium |
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An acidic buffer is prepared by mixing:
1. weak acid and it's salt with strong base
2. equal volumes of equimolar solutions of weak acid and weak base
3. strong acid and it's salt with strong base
4. strong acid and it's salt with weak base
(The pKa of acid = pKb of the base)
Subtopic:  Buffer |
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For a weak acid HA, the percentage of dissociation is nearly 1% at equilibrium. If the concentration of acid is 0.1 mol L-1, then the correct option for its Ka at the same temperature will be:
1. \(1 \times 10^{-4}\)    
2. \(1 \times 10^{-6} \)
3. \(1 \times 10^{-5} \)
4. \(1 \times 10^{-3} \)
Subtopic:  Ionisation Constant of Acid, Base & Salt |
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The pH of the solution containing 50 mL each of 0.10 M sodium acetate and 0.01 M acetic acid is: [Given pKa of CH3COOH = 4.57]
1. 2.57 2. 5.57
3. 3.57 4. 4.57
Subtopic:  pH calculation |
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\(3 \mathrm{O}_{2}(\mathrm{~g}) \rightleftharpoons 2 \mathrm{O}_{3}(\mathrm{g}) \) 
For the above reaction at 298 K, \(K_c\) is found to be \(3.0 \times 10^{-59} \). If the concentration of \(O_2\) at equilibrium is 0.040 M, then the concentration of \(O_3 \) in M is: 
1. \(1.2 \times 10^{21} \)
2. \(4.38 \times 10^{-32} \)
3. \(1.9 \times 10^{-63} \)
4. \(2.4 \times 10^{31} \)

Subtopic:  Introduction To Equilibrium |
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The solubility product of \(BaSO_4\) in water is \(1.5 \times 10^{-9} \). The molar solubility of \(BaSO_4\) in 0.1 M solution of Ba(NO3)2 in- 
1. \(2.0 \times 10^{-8} M\)
2. \(0.5 \times 10^{-8} M\)
3. \(1.5 \times 10^{-8} M\)
4. \(1.0 \times 10^{-8} M\)

Subtopic:  Solubility Product |
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Consider the following reaction taking place in 1L capacity container at 300 K.
\(A +B \rightleftharpoons C+D \)
If one mole each of A and B are present initially and at equilibrium 0.7 mol of C is formed, then the equilibrium constant \((K_c) \) for the reaction is

1. 9.7  2. 1.2 
3. 6.2  4. 5.4 
Subtopic:  Introduction To Equilibrium |
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If 0.01 M acetic acid solution is 1% ionised, then pH of this acetic acid solution is :
1. 3 2. 2
3. 4 4. 1
Subtopic:  pH calculation |
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Kp for the following reaction is 3.0 at 1000 K.
\(CO_{2}(g)\,+\,C(s)\rightarrow \,2CO(g)\)
The value of Kfor the reaction at the same temperature is: 
(Given - R = 0.083 L bar K-1 mol-1)
1. 0.36 2. 3.6 × 10-2
3. 3.6 × 10-3 4. 3.6
Subtopic:  Introduction To Equilibrium |
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