The correct statement about the SN1 reaction is:
1. | 100 % racemisation. |
2. | Inversion more than retention leads to partial racemisation. |
3. | 100 % retention. |
4. | 100 % Inversion. |
Which of the following statements is not correct for a nucleophile?
1. Nucleophile is a Lewis acid.
2. Ammonia is a nucleophile.
3. Nucleophiles attack low electron density sites.
4. Nucleophiles are not electron-seeking.
Two possible stereo-structures of CH3CHOH.COOH, which are optically active, is called?
1. | Diastereomers | 2. | Atropisomers |
3. | Enantiomers | 4. | Mesomers |
In Duma's method for estimation of nitrogen, 0.25 g of an organic compound gave 40 mL of nitrogen collected at 300 K temperature and 725 mm pressure. If the aqueous tension at 300 K is 25 mm, the percentage of nitrogen in the compound is:
1. | 17.36 | 2. | 18.20 |
3. | 16.76 | 4. | 15.76 |
In which of the following compounds, the C—Cl bond ionization shall give the most stable carbonium ion?
1. | 2. | ||
3. | 4. |
Consider the following compounds-
Hyperconjugation occurs in:
1. | I only | 2. | II only |
3. | III only | 4. | I and III |
The enolic form of ethyl acetoacetate is given below-
The number of σ and π bonds in the enolic form are respectively:
1. 18 sigma bonds and 2 pi-bonds
2. 16 sigma bonds and 1 pi-bond
3. 9 sigma bonds and 2 pi-bonds
4. 9 sigma bonds and 1 pi-bond
1. | 4 | 2. | 8 |
3. | 12 | 4. | 16 |
In Kjeldahl’s method for estimation of nitrogen present in the soil sample, ammonia evolved from 0.75g of sample neutralized 10ml. of 1M H2SO4. The percentage of nitrogen in the soil is:
1. | 37.33 | 2. | 45.85 |
3. | 25.75 | 4. | 43.13 |
The structure of the compound whose IUPAC name is 3-Ethyl-2-hydroxy-4-methylhex-3-en-5-ynoic acid is:
1. | 2. | ||
3. | 4. |