An aromatic compound ‘A’ on treatment with ammonia and heating forms compound ‘B’ which on heating with Br₂ and KOH forms a compound ‘C’ of molecular formula C₆H₇N. The Substrate A is -

1. Aniline

2. Benzoic acid 

3. Benzamide

4. Benzamine

Chlorobenzene $\stackrel{{\mathrm{HNO}}_3, {\mathrm{H}}_2{\mathrm{SO}}_4}{\to }$ X $\stackrel{{\mathrm{H}}_2/\mathrm{Pd}}{\to }$ Y

X and Y in the above sequence are-

1. 1-chloro-4-nitrobenzene, and nitrobenzene

2. 1-chloro-3-nitrobenzene, and 4-chloroaniline

3. 1-chloro-4-nitrobenzene, and 4-chloroaniline

4. 1-chloro-3-nitrobenzene, and nitrobenzene

${}_{}$\(\small{\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{I} \xrightarrow[]{NaCN} \mathrm{CH}_3 \mathrm{CH}_2 \mathrm{CN}\xrightarrow[]{{OH}^{-},Partial hydrolysis} A \xrightarrow[NaOH]{{Br}_2} \mathrm{B}}\)

The molecular formulae of A, and B in the above reaction are-

$1. {\mathrm{CH}}_3{\mathrm{CH}}_2\mathrm{COOH}, \mathrm{and} {\mathrm{CH}}_3\mathrm{CH}\left(\mathrm{Br}\right)\mathrm{COOH}$
$2. {\mathrm{CH}}_3{\mathrm{CH}}_2\mathrm{COOH}, \mathrm{and} {\mathrm{CH}}_3{\mathrm{CH}}_2\mathrm{COBr}$
$3. {\mathrm{CH}}_3{\mathrm{CH}}_2{\mathrm{CONH}}_2, \mathrm{and} {\mathrm{CH}}_3{\mathrm{CH}}_2{\mathrm{NH}}_2$
$4. {\mathrm{CH}}_3{\mathrm{CH}}_2{\mathrm{CONH}}_2, \mathrm{and} {\mathrm{CH}}_3{\mathrm{CH}}_2{\mathrm{CH}}_2{\mathrm{NH}}_2$

$\mathrm{A}\stackrel{{\mathrm{NH}}_3, ∆}{\to } {\mathrm{CH}}_3{\mathrm{CONH}}_2 \stackrel{\mathrm{NaOBr}}{\to } \mathrm{B}\stackrel{{\mathrm{NaNO}}_2/\mathrm{HCl}}{\to } {\mathrm{CH}}_3\mathrm{OH}$

A and B in the above reaction sequence are :

$1. {\mathrm{CH}}_3{\mathrm{CH}}_2\mathrm{OH}, \mathrm{and} {\mathrm{CH}}_3{\mathrm{CH}}_2{\mathrm{N}}_2\mathrm{Cl}$
$2. {\mathrm{CH}}_3\mathrm{COOH}, \mathrm{and} {\mathrm{CH}}_3{\mathrm{CH}}_2{\mathrm{NH}}_2$
$3. {\mathrm{CH}}_3\mathrm{COOH}, \mathrm{and} {\mathrm{CH}}_3{\mathrm{NH}}_2$
$4. {\mathrm{CH}}_3{\mathrm{CH}}_2\mathrm{Br}, \mathrm{and} {\mathrm{CH}}_3{\mathrm{NH}}_2$

The incorrect statement among the following is :