Q. No.
Vanillin, used as a flavouring agent, is:
1. An Aliphatic alcohol
2. An Aromatic aldehyde
3. A Hydrocarbon
4. A Carbohydrate
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A compound that can be reduced to the corresponding hydrocarbon by Zn-Hg/ conc. HCl is:
1. Butan-2-one
2. Acetic acid
3. Acetamide
4. Ethyl acetate
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The most reactive compound towards the nucleophilic addition reaction is:
| 1. | Benzaldehyde | 2. | p-Tolualdehyde |
| 3. | p-Nitrobenzaldehyde | 4. | Acetophenone |
2-Methyl propene on oxidation with hot KMnO4 gives:
1. Acetone
2. Ethanoic acid
3. CO2 and H2O
4. Both 1 & 3
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The compounds that undergoes the Cannizzaro reaction are:
(i) Methanal
(ii) 2-Methylpentanal
(iii) Benzaldehyde
(iv) Benzophenone
1. (i)
2. (ii)
3. (i), (iii)
4. (i), (ii), (iii)
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Match the common names given in Column I with the IUPAC names given in Column II.
| Column l (Common names) |
Column ll (IUPAC names) |
| A. Cinnamaldehyde | 1. Pentanal |
| B. Acetophenone | 2. Prop-2-enal |
| C. Valeraldehyde | 3. 1-Phenylethanone |
| D. Acrolein | 4. 3-Phenylprop-2-en-al |
Codes:
| A | B | C | D | |
| 1. | 2 | 3 | 4 | 1 |
| 2. | 3 | 1 | 4 | 2 |
| 3. | 1 | 4 | 3 | 2 |
| 4. | 4 | 3 | 1 | 2 |
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1. Tollens' test
2. Fehling’s test
3. Iodoform test
4. Sodium bicarbonate test.
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The reaction that does not give benzoic acid as the major product is:
| 1. |  \(\xrightarrow{K_2Cr_2O_7}\) |
2. |  \(\xrightarrow[(ii)H_3O^+]{(i)NaOCl}\) |
| 3. | \(\xrightarrow{PCC}\) |
4. | \(\xrightarrow{KMnO_4/H^+}\) |
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The correct statement among the following about HCOOH is:
1. It is a stronger acid than CH3COOH
2. It reduces Tollen’s reagent
3. It gives CO and H2O on heating with conc.H2SO4
4. All of the above
Match the acids given in Column-I with their correct IUPAC names given in Column-II and mark the appropriate option:
| Column-l (Acids) |
Column-ll (IUPAC names) |
||
| A. | Phthalic acid | 1. | Hexane-1,6-dioic acid |
| B. | Glutaric acid | 2. | Benzene-1,2-dicarboxylic acid |
| C. | Succinic acid | 3. | Pentane-1,5-dioic acid |
| D. | Adipic acid | 4. | Butane-1,4-dioic acid |
Codes:
| A | B | C | D | |
| 1. | 2 | 3 | 4 | 1 |
| 2. | 3 | 1 | 4 | 2 |
| 3. | 1 | 4 | 3 | 2 |
| 4. | 4 | 3 | 2 | 1 |
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