Which of the following lanthanoids is radioactive?
1. Promethium
2. Europium
3. Plutonium
4. Neptunium
From the following, which is the most basic hydroxide?
1. Ce(OH)3
2. Lu(OH)3
3. Yb(OH)3
4. Tb(OH)3
The incorrect statement regarding the lanthanons is ;
| 1. | Europium shows +2 oxidation state |
| 2. | The basicity decreases as the ionic radius decreases from Pr to Lu |
| 3. | All the lanthanons are much more reactive than aluminium |
| 4. | Ce (+4) solutions are widely used as oxidising agents in volumetric analysis |
The correct electronic configuration of Gadolinium(Atomic number = 64) is :
1. [Xe]4f86d2
2. [Xe]4f95s1
3. [Xe]4f75d16s2
4. [Xe]4f65d26s2
| 1. | [Xe] 4f6 5d1 6s2, [Xe]4f7 5d1 6s2, and [Xe] 4f9 6s2
|
| 2. | [Xe] 4f6 5d1 6s2, [Xe] 4f75d1 6s2, and [Xe]4f8 5d1 6s2
|
| 3. | [Xe] 4f7 6s2, [Xe]4f7 5d1 6s2, and [Xe] 4f9 6s2
|
| 4. | [Xe] 4f7 6s2, (Xe]4f8 6s2, and [Xe]4f8 5d1 6s2 |
Gadolinium belongs to 4f series. It’s atomic number is 64. Which of the following is the correct electronic configuration of gadolinium?
| 1. | \(\text{ [Xe] } 4f^8 6 d^2\) | 2. | \(\text { [Xe]}4 f^9 5 s^1\) |
| 3. | \(\text { [Xe] } 4f^7 5 d^1 6 s^2\) | 4. | \(\text { [Xe]} 4f^6 5 d^2 6 s^2\) |
A pair among the following have nearly the same atomic radii:
(Numbers in the parenthesis are atomic numbers).
| 1. | Ti (22) and Zr (40) | 2. | Zr (40) and Nb (41) |
| 3. | Zr (40) and Hf (72) | 4. | Zr (40) and Ta (73) |
| 1. | The greater metallic character of the lanthanoids than that of the corresponding actinoids. |
| 2. | More energy difference between 5f and 6d orbitals than that between 4f and 5d orbitals. |
| 3. | The lesser energy difference between 5f and 6d orbitals than that between 4f and 5d orbitals. |
| 4. | More active nature of the actinoids. |
Which one of the following is a diamagnetic ion?
| 1. | La3+ | 2. | Lu3+ |
| 3. | Ce4+ | 4. | All of the above. |
The unpaired electron in Eu3+ will be the same in:
1. Yb2+
2. Ho3+
3. Sm2+
4. Gd3+