The pair of ions having the same electronic configuration is -

1.  Cr3+, Fe3+

2.  Fe3+, Mn2+

3.  Fe3+, Co3+

4.  Sc3+, Cr3+

Hint: Draw the electronic configuration of each ion and  check the same configuration

The electronic configuration of ions is as follows:

Cr24=[Ar]3d5, 4s1
Fe26=[Ar]3d6, 4s2
Mn25=[Ar]3d5, 4s2
Co27=[Ar]3d7, 4s2
Sc21=[Ar]3d1, 4s2   Cr3+24=[Ar]3d3
Fe3+26=[Ar]3d5
Mn2+25=[Ar]3d5
Co3+27=[Ar]3d6
Sc3+21=[Ar]
 
Thus, Fe3+ and Mn2+ have the same electronic configuration.