Which of the following solutions has the highest
equivalent conductance?
1. 0.01 M NaCl
2. 0.05 M NaCl
3. 0.005 M NaCl
4. 0.02 M NaCl
A solution of Na2SO4 in water is electrolysed
using pt electrodes. The products at the cathode
and anod are respectively
1. H2, SO2
2. O2, NaOH
3. H2, O2
4. O2, SO2
The reduction potential of the two half cell
reactions (occuring in an electrochemical cell)
are
PbSO4(s) + 2e– Pb(s) + (aq) (E°= –0.31V)
Ag+(aq) + e– Ag(s) (E° = 0.80V)
The feasible reaction will be
1. Pb(s) + (aq) + 2 Ag+(aq) 2Ag (s) + PbSO4 (s)
2. PbSO4(s) + Ag+ (aq) Pb(s)+(aq) + 2Ag(s)
3. Pb(s) + (s) + Ag(s) Ag+(aq) + PbSO4(s)
4. PbSO4(s) +Ag(s) Ag+(aq) + Pb(s) + (aq)
The emf of the cell
Tl | Tl+ (0.001 M) || Cu2+ (1M) | Cu is 0.83V. The
emf of this cell could be increased by
1. Increasing in the concentration of Tl+ ions
2. Increasing in the concentration of Cu+ ions
3. Increasing in the concentration of both
4. None of the above
For a reaction A(s) + 2B+ A2+ + 2B(s) ; KC has been found to be 1012. The is :
1. | 0.35 V | 2. | 0.71 V |
3. | 0.01 V | 4. | 1.36 V |
The solution of nickel sulphate in which nickel
rod dipped is diluted to 10 times. The potential
of nickel
1. Decreases by 60 mV
2. Increases by 30 mV
3. Decreases by 30 mV
4. Decreases by 60 mV
Two electrodes are fitted in conductance cell
1.5cm apart while the area of cross-section of
each electrode is 0.75 cm2. The cell constant is
1. 1.0125
2. 0.5cm
3. 2.0cm–1
4. 0.2 cm–1
Pick out the incorrect statement
1. Equivalent conductance increase with dilution
2. Molar conductance increase with dilution
3. Specific conductance increase with dilution
4. Specific resistance increase with dilution
In passing 3 faraday of electricity through the
three electrolytic cells connected in series
containing Ag+, Cu2+ and Al3+ respectively. The
molar ratio in which the three metal ions are
liberated at the electrode is
1. 1 : 2 : 3
2. 3 : 2 : 1
3. 6 : 3 : 2
4. 3 : 4 : 2
During electrolysis of fused calcium hydride, the
hydrogen is produced at
1. Cathode
2. Anode
3. Hydrogen is not liberated at all
4. H2 produced reacts with oxygen to form water
The current liberates 0.504 g of hydrogen in 2
hours, the amount of copper liberated from a
solution of CuSO4 by the same current flowing
for the same time would be
1. 31.8g
2. 63.6g
3. 15.9g
4. 6.36g
Given that
I2 + 2e¯ 2I¯; E° = 0.54V
Br2 + 2e¯ 2Br¯; E° = 1.09V
Predict which of the following is true
1. I¯ ions will be able to reduce bromine
2. Br¯ ion will be able to reduce iodine
3. Iodine will be able to reduce bromide ions
4. Bromine will be able to reduce iodide ions
The potential of hydrogen electrode having a
pH = 10 is
1. 0.59V
2. –0.59V
3. zero volts
4. –0.059V
What is the EMF of the cell?
Zn(s) | Zn+2 (0.1M) || Sn+2 (0.001M) | Sn(s)
Given
1. 0.62V
2. 0.56V
3. 1.12V
4. 0.31V
Zinc gives H2 with H2SO4 and HCl but not with
HNO3 because
1. Zinc acts as oxidising agent when reacts with
HNO3
2. HNO3 is a weaker acid then H2SO4 and HCl
3. In electrochemical series zinc is above
hydrogen
4. is reduced is preference to hydronium ion